Some magnetic materials undergo a first-order phase transition when a magnetic induction field B is applied. These

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Some magnetic materials undergo a first-order phase transition when a magnetic induction field B is applied. These materials are of interest because some of them have a strong magnetocaloric effect, which could be used for refrigeration applications [134]. In these materials, at any given temperature T, there is a critical magnetic induction field B in which the two phases coexist. The two phases, labelled 1 and 2, are characterised by their molar magnetisation m1 and m2 and their molar entropies per unit volume s1 and s2. Show that the temperature derivative of the magnetic induction field B satisfies the magnetic Clausius–Clapeyron equation,imagewhich is analogous to the Clausius–Clapeyron equation (6.49).

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Principles Of Thermodynamics

ISBN: 9781108426091

1st Edition

Authors: Jean-Philippe Ansermet, Sylvain D. Brechet

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