Suppose that a system of N atoms of type A is placed in diffusive contact with a

Question:

Suppose that a system of N atoms of type A is placed in diffusive contact with a system of N atoms of type B at the same temperature and volume. Show that after diffusive equilibrium is reached the total entropy is increased by 2N log 2. The entropy increase 2N log 2 is known as the entropy of mixing. If the atoms are identical (A ≡ B), show that there is no increase in entropy when diffusive contact is established. The difference in the results has been called the Gibbs paradox.

Fantastic news! We've Found the answer you've been seeking!

Step by Step Answer:

Related Book For  book-img-for-question

Thermal Physics

ISBN: 978-0716710882

2nd Edition

Authors: Charles Kittel, Herbert Kroem

Question Posted: