(a) An aqueous solution of pure stereoisomer X of concentration 0.10 g mL-1 had an observed rotation...
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(b) Under identical conditions but with concentration 0.050 g mL-1, a solution of X had an observed rotation of +165o. Rationalize how this could be and recalculate [a]D for stereoisomer X.
(c) If the optical rotation of a substance studied at only one concentration is zero, can it definitely be concluded to be achiral? Racemic?
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Organic Chemistry
ISBN: 978-1118133576
11th edition
Authors: Graham Solomons, Craig Fryhle, Scott Snyder
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