Alkyl halides can be reduced to alkanes by a radical reaction with tributyltin hydride, (C 4 H
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Alkyl halides can be reduced to alkanes by a radical reaction with tributyltin hydride, (C4H9)3SnH, in the presence of light (hv). Propose a radical chain mechanism by which the reaction might occur. The initiation step is the light- induced homolytic cleavage of the Sn?H bond to yield a tributyltin radical.
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hv + (C4H9)3SnX R-H (CHg)3SnH R-X
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