Question: Explore the conditions under which the 'integral' approximation for the translational partition function is not valid by considering the translational partition function of an Ar

Explore the conditions under which the 'integral' approximation for the translational partition function is not valid by considering the translational partition function of an Ar atom in a cubic box of side 1.00 cm. Estimate the temperature at which, according to the integral approximation, q = 10 and evaluate the exact partition function at that temperature.

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V 4 and hence T A 2 mmk 2 3 h 2mmkT2 n1 qe1AB8m1 Then q 6626 x 1034 Js ... View full answer

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