Para-nitrosation of N,N-dimethylaniline (C-nitrosation) is believed to take place through an electrophilic attack by N+O ions. (a)
Question:
Para-nitrosation of N,N-dimethylaniline (C-nitrosation) is believed to take place through an electrophilic attack by N+O ions.
(a) Show how N+O ions might be formed in an aqueous solution of NaNO2 and HCl.
(b) Write a mechanism for p-nitrosation of N,N-dimethylaniline.
(c) Tertiary aromatic amines and phenols undergo C-nitrosation reactions, whereas most other benzene derivatives do not. How can you account for this difference?
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a b c The NO ion is a weak electrophile For it ...View the full answer
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Related Book For 
Organic Chemistry
ISBN: 978-1118133576
11th edition
Authors: Graham Solomons, Craig Fryhle, Scott Snyder
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