Assume two species can associate in the vapor phase according to the reactions Using the notation that

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Assume two species can associate in the vapor phase according to the reactions

iA A i = 1,2, etc. jB = B j= 1,2, etc. iA +jB = AB = but not all integers need be included

Using the notation that G̅A and G̅B are the partial molar Gibbs energies of the total species A and B (in all its forms, unassociated and associated), prove that

GAGA and GB = GB

where G̅A1 and G̅B1 are the partial molar Gibbs energies of the monomeric species, respectively. Also prove that

fA=fA and B = fB

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