Derive the analogues of the Gibbs-Duhem equations (Eqs. 8.2-8 and 8.2-9) for the constraints of a.Constant temperature

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Derive the analogues of the Gibbs-Duhem equations (Eqs. 8.2-8 and 8.2-9) for the constraints of

-N P,Ni C v (OP) dP+ N; d0; = 0 T,Ni i=1 dT - N N 20 ( ) - () dT T P,Ni T,Ni C dP+Ex; d0; = 0 i=1

C Nidir p = 0 i=1 C ;di; p = 0 = i=1 (8.2-9a) (8.2-9b)

a.Constant temperature and volume

b. Constant internal energy and volume

c. Constant entropy and volume

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Chemical Biochemical And Engineering Thermodynamics

ISBN: 9780470504796

5th Edition

Authors: Stanley I. Sandler

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Question Posted: Nov 17, 2023 07:50 AM

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Derive the analogues of the Gibbs-Duhem equations (Eqs. 8.2-8 and 8.2-9) for the constraints of a.Constant temperature

Question:

-N от P,Ni C v (OP) ₁ dP+ ► N; d0; = 0 T,Ni i=1 dT - N N 20 ( ) ат - (р) dT ӘT P,Ni T,Ni C dP+Ex; d0; = 0 i=1 (8.2-8a) (8.2-8b)

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Chemical Biochemical And Engineering Thermodynamics

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