In Sec. 8.7 we established that the condition for equilibrium between two phases is for closed systems

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In Sec. 8.7 we established that the condition for equilibrium between two phases is 

G = G(for all species present in both phases)

for closed systems either at constant temperature and pressure or at constant internal energy and volume. 

Show that this equilibrium condition must also be satisfied for closed systems at 

a. Constant temperature and volume 

b. Constant entropy and volume

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