Suppose we have a volume of nitrogen plus a small amount of water vapor at (1.0 mathrm{~atm}).

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Suppose we have a volume of nitrogen plus a small amount of water vapor at \(1.0 \mathrm{~atm}\). The walls of the container are at \(25^{\circ} \mathrm{C}\), and there is a hot pipe at \(105^{\circ} \mathrm{C}\) running through the volume. Explain the behavior predicted by Eq. (15-4a), the behavior predicted by Eq. (15-4b), and the reasons that Eq. (15-4b) more closely predicts reality.

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