(a) From data in Appendix 2A and Table 4C.1, derive a numerical form of the ClausiusClapeyron equation...

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(a) From data in Appendix 2A and Table 4C.1, derive a numerical form of the Clausius–Clapeyron equation for benzene.

(b) Use the equation to plot the appropriate quantities that should give a straight-line relation between vapor pressure and temperature.

(c) Estimate the boiling point of benzene when the external pressure is 0.655 atm.

(d) Calculate Sm° for gaseous benzene.2A THERMODYNAMIC DATA AT 25 C Inorganic Substances Substance Aluminum Al(s) Al+ (aq) Al(OH)3(S) AlO3(s)

TABLE 4C.1 Standard Enthalpies of Physical Change* AH fus% (kJ.mol-) Substance Formula acetone ammonia argon

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Chemical Principles The Quest For Insight

ISBN: 9781464183959

7th Edition

Authors: Peter Atkins, Loretta Jones, Leroy Laverman

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