Wavefunctions corresponding to states of different energy of a particle in a box are mutually orthogonal in

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Wavefunctions corresponding to states of different energy of a particle in a box are mutually “orthogonal” in the sense that, if the two wavefunctions are multiplied together and then integrated over the length of the box, the outcome is zero.

(a) Confirm that the wavefunctions for n = 1 and n = 2 are orthogonal. 

(b) Demonstrate, without doing a calculation, that all wavefunctions with even n are orthogonal to all wavefunctions with odd n.

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Chemical Principles The Quest For Insight

ISBN: 9781464183959

7th Edition

Authors: Peter Atkins, Loretta Jones, Leroy Laverman

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