For the reaction A B, the ratio of products to reactants at equilibrium is always the

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For the reaction A → B, the ratio of products to reactants at equilibrium is always the same number, no matter how much A or B is initially present. Interestingly, in contrast, the ratio of products to reactants for the reaction C → 2 D does depend on how much of C and D you have initially. Explain this observation.

Which ratio is independent of the starting amounts of C and D? Answer in complete sentences.

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