The initial concentration and K a of several weak acid (HA) solutions are listed. For which solution

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The initial concentration and Ka of several weak acid (HA) solutions are listed. For which solution is the x is small approximation least likely to work in finding the pH?

(a) Initial [HA] = 0.100 M; Ka = 1.0 * 10-5

(b) Initial [HA] = 1.00 M; Ka = 1.0 * 10-6

(c) Initial [HA] = 0.0100 M; Ka = 1.0 * 10-3

(d) Initial [HA] = 1.0 M; Ka = 1.5 * 10-3

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