These sets of quantum numbers are each supposed to specify an orbital. One set, however, is erroneous.

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These sets of quantum numbers are each supposed to specify an orbital. One set, however, is erroneous. Which one and why?

(a) n = 3; l = 0; ml = 0 

(b) n = 2; l = 1; ml = -1

(c) n = 1; l = 0; ml = 0 

(d) n = 4; l = 1; ml = -2

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