Refer to the figure below and Figure 20.25, which show the fraction of species in solution [alpha

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Refer to the figure below and Figure 20.25, which show the fraction of species in solution [alpha (α)] as a function of pH. The following questions are in regard to the equilibria involved in an aqueous solution of H2CO3 (dissolved CO2) in fresh water at 25°C.
(a) At what pH does [H2CO3(aq)] = [HCO3]?
(b) At what pH does [HCO3] = [CO32−]?
(c) What is the predominant species in solution when the solution has a pH of 8?
(d) What species are in solution when the solution has a pH of 7?

Alpha 1.00 0.80 0.60 0.40 0.20 0.00 Fraction of HCO3 Fraction of HCO3 Fraction of CO3- 2- 3 5 7 9 11 13 PH

Data given in Figure 20.25

At low pH, CO is the dominant species. As the pH increases, the bi- carbonate ion concentration increases to

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Chemistry And Chemical Reactivity

ISBN: 9780357001172

10th Edition

Authors: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

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