HBr is oxidized in the following reaction: (a) Show that this mechanism can account for the correct

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HBr is oxidized in the following reaction:

4 HBr(g) + O(g)  2 HO(g) + 2 Br(g) A proposed mechanism is HBr + O  HOOBr HOOBr + HBr  2 HOBr HOBr + HBr  HO


(a) Show that this mechanism can account for the correct stoichiometry.
(b) Identify all intermediates in this mechanism.
(c) What is the molecularity of each elementary step?
(d) Write the rate expression for each elementary step.
(e) Identify the rate-determining step.

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Chemistry For Engineering Students

ISBN: 9780357026991

4th Edition

Authors: Lawrence S. Brown, Tom Holme

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