Disulfides are compounds that have S-S bonds, like peroxides have O-O bonds. Thiols are organic compounds that
Question:
Disulfides are compounds that have S-S bonds, like peroxides have O-O bonds. Thiols are organic compounds that have the general formula R-SH, where R is a generic hydrocarbon. The SH- ion is the sulfur counterpart of hydroxide, OH-. Two thiols can react to make a disulfide, R-S-S-R.
(a) What is the oxidation state of sulfur in a thiol?
(b) What is the oxidation state of sulfur in a disulfide?
(c) If you react two thiols to make a disulfide, are you oxidizing or reducing the thiols?
(d) If you wanted to convert a disulfide to two thiols, should you add a reducing agent or oxidizing agent to the solution?
(e) Suggest what happens to the H’s in the thiols when they form disulfides.
Step by Step Answer:
Chemistry The Central Science
ISBN: 978-0134414232
14th Edition
Authors: Theodore Brown, H. LeMay, Bruce Bursten, Catherine Murphy, Patrick Woodward, Matthew Stoltzfus