A gas has an ideal gas heat capacity of C P * = (7/2)R and is described

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A gas has an ideal gas heat capacity of CP* = (7/2)R and is described by the equation of state:  Z = 1 + (CP 2)/(RT) with C = 100 cm3/bar · mol.

A. Find a general expression for the residual molar enthalpy for this gas.

B. Find a general expression for the residual molar entropy for this gas.

C. Find ΔH and ΔS for the gas if it is isothermally compressed from P = 1 bar and T = 400 K to P = 50 bar and T = 400 K. Problems 14 through 17 involve a gas that follows the equation of state:V RT P + aTPwith a = 0.3 cm3/mol · bar 2 · K. The gas has a molecular mass of 120 g/mol and an ideal gas heat capacity CP* = 40 J/mol.

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