Assume that the seawater sample described in Example 18-6 contains approximately 440 g Ca 2+ per metric

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Assume that the seawater sample described in Example 18-6 contains approximately 440 g Ca2+ per metric ton (1 metricton = 103 kg; density of seawater = 1.03 g/mL)

(a) Should Ca(OH)2(s) precipitate from seawater under the stated conditions, that is, with [OH-] = 2.0 x 10‾3 M?

(b) Is the separation of Ca2+ from Mg2+ in seawater feasible?


Example 18-6

The first step in a commercial process in which magnesium is obtained from seawater involves precipitating Mg2+ as Mg(OH)2(s). The magnesium ion concentration in seawater is about 0.059 M. If a seawater sample is treated so that its [OH‾] is maintained at 2.0 x 10‾3 M, 

(a) what will be [Mg2+] remaining in solution when precipitation stops (Ksp = 1.8 x 10‾11)?

(b) Is the precipitation of Mg(OH)2(s) complete under these conditions?

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General Chemistry Principles And Modern Applications

ISBN: 9780132931281

11th Edition

Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette

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