The two common chlorides of phosphorus, PCl 3 and PCl 5 , both important in the production

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The two common chlorides of phosphorus, PCl3 and PCl5, both important in the production of other phosphorus compounds, coexist in equilibrium through the reaction

PC13(g) + Cl(g)  PC15(g)

At 250 °C, an equilibrium mixture in a 2.50 L flask contains 0.105 g PCl5, 0.220 g PCl3, and 2.12 g Cl2. What are the values of 

(a) Kc and 

(b) Kp for this reaction at 250 °C ? 

For (b), use partial pressures in atmospheres.

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General Chemistry Principles And Modern Applications

ISBN: 9780132931281

11th Edition

Authors: Ralph Petrucci, Jeffry Madura, F. Herring, Carey Bissonnette

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