(a) The reaction of ScCl 3 nTHF with one equivalent of ligand 27.19 yields a neutral compound...

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(a) The reaction of ScCl3·nTHF with one equivalent of ligand 27.19 yields a neutral compound A in which the metal is octahedrally sited. A reacts with three equivalents of MeLi to give B. Suggest structures for A and B. What is the oxidation state of the metal in each compound?

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(b) The complex [(η5-C5H5)2La{C6H3-2,6-(CH2NMe2)2}] is 5-coordinate. Suggest, with reasoning, a structure for the complex.

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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