For each of the following clusters, confirm that the total valence electron count is consistent with the
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For each of the following clusters, confirm that the total valence electron count is consistent with the metal cage framework adopted:
(a) [Ru6(CO)18]2−, octahedron;
(b) H4Ru4(CO)12, tetrahedron;
(c) Os5(CO)16, trigonal bipyramid;
(d) Os4(CO)16, square;
(e) Co3(CO)9(μ3-CCl), triangle;
(f) H2Os3(CO)9(μ3-PPh), triangle;
(g) HRu6(CO)17B, octahedron;
(h) Co3(η5-Cp)3(CO)3, triangle;
(i) Co3(CO)9Ni(η5-Cp), tetrahedron.
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