Group theory is often used by chemists as an aid in the interpretation of IR spectra. For
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Group theory is often used by chemists as an aid in the interpretation of IR spectra. For example, there are four NH bonds in NH4+ and four stretching modes are possible. There is the possibility that several vibrational modes occur at the same frequency, and hence are degenerate. A quick glance at the character table will tell if degeneracy is possible.
(a) In the case of the tetrahedral NH4+ ion, is it necessary to consider the possibility of degeneracies?
(b) Are degeneracies possible in any of the vibrational modes of NH2D2+?
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Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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