The compound [Ni( 5 -C 5 H 5 ) 2 ] readily adds one molecule of HF

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The compound [Ni(η5-C5H5)2] readily adds one molecule of HF to yield [Ni(η5-C5H5)(η4-C5H6)]+, whereas [Fe(η5-C5H5)2] reacts with strong acid to yield [Fe(η5-C5H5)2H]+. In the latter compound the H atom is attached to the Fe atom. Provide a reasonable explanation for this difference.

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Inorganic Chemistry

ISBN: 9780198768128

7th Edition

Authors: Mark Weller, Tina Overton, Jonathan Rourke

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