BH 3 and PH 3 each contain four atoms, with the three hydrogens surrounding the central atom.

Question:

BH3 and PH3 each contain four atoms, with the three hydrogens surrounding the central atom. Do the two molecules have the same electron-group geometry? Do they have the same molecular shape? Name the geometry and the shape for both molecules. You know from Problem 6.59 that PH3 is nonpolar. What about BH3? Is it polar or nonpolar? Explain.


Data from Problem 6-59

Consider the PX3 molecule, where X is either H or F.

(a) For X = H, the entire molecule is nonpolar. Why is this so?

(b) For X = F, the entire molecule is polar. Draw two molecules next to one another in proper orientation so as to yield a dipolar intermolecular attraction, and explain why the attraction occurs.

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Related Book For  book-img-for-question

Introductory Chemistry Atoms First

ISBN: 9780321927118

5th Edition

Authors: Steve Russo And Michael Silver

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