Determine the translational, rotational, and vibrational contributions toward the molar entropy and the molar specific heat of
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Determine the translational, rotational, and vibrational contributions toward the molar entropy and the molar specific heat of carbon dioxide at NTP. Assume the ideal-gas formulae and use the following data: molecular weight \(M=44.01\); moment of inertia \(I\) of a \(\mathrm{CO}_{2}\) molecule \(=71.67 \times\) \(10^{-40} \mathrm{~g} \mathrm{~cm}^{2}\); wave numbers of the various modes of vibration: \(\bar{v}_{1}=\bar{v}_{2}=667.3 \mathrm{~cm}^{-1}, \bar{v}_{3}=\) \(1383.3 \mathrm{~cm}^{-1}\), and \(\bar{v}_{4}=2439.3 \mathrm{~cm}^{-1}\).
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