Question: Are two-electron transitions permitted by electric dipole selection rules? To arrive at your answer, first consider the wavefunction to be a simple product of spinorbitals.

Are two-electron transitions permitted by electric dipole selection rules? To arrive at your answer, first consider the wavefunction to be a simple product of spin–orbitals. (This is called a Hartree product.) Is your conclusion different if the state is represented by one or more Slater determinants?

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In the context of atomic and molecular physics the concept of electric dipole selection rules refers to the allowed or forbidden nature of transitions ... View full answer

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