In The Chemistry of Complex Cross Couplings we showed a Heck reaction used in the synthesis of

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In “The Chemistry of… Complex Cross Couplings” we showed a Heck reaction used in the synthesis of ecteinascidin 743, a natural compound with anticancer activity isolated from the marine tunicate Ecteinascidia turbinate. Write a mechanism for this reaction, using PdL2 to represent the palladium catalyst and abbreviating the complicated structures of the ecteinascidin synthetic intermediates as appropriate.

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Organic Chemistry

ISBN: 978-1118875766

12th Edition

Authors: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder

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