(a) Consider the second propagation step for peroxide-promoted HBr addition to an alkene (Eq. 5.52b). Calculate the...
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(a) Consider the second propagation step for peroxide-promoted HBr addition to an alkene (Eq. 5.52b). Calculate the ΔH° for this reaction.
(b) Calculate the ΔH° for the same step using HCl instead of HBr.
(c) Use your calculation to explain why no peroxide effect is observed for the addition of HCl to an alkene.
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