Complete each reaction given in Fig. P18.70, by giving the major organic product(s), and explain your reasoning.

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Complete each reaction given in Fig. P18.70, by giving the major organic product(s), and explain your reasoning. “No reaction” may be an appropriate response.(a) (b) (c) (d) ON- ON. Cl NO CH3CH- -F + CH3CHS- NO + -OH -B(OH)2 OH -Cl + CH3CHCH-NH NaOH solution HO+ CH3

HO. -OTf OH pyrogallol + (HO)B- OH + Br CCL14 NO Pd(PPH3)4 catalyst aqueous NaCO3 (C6H5O3Br)

(h) (j) (1) OH triflic anhydride, pyridine 0C HC C= OX CH0-C Br + KCrO7 H OH os m-chlorophenol + NaCrO7

(m) (n) Br. Br CH0- NO NO +(CH3)2CHCHS- (0) Give the stereochemistry of the product. HOCH2 (CH3)3C-CH=CH + H

(q) Give the stereochemistry of the product and explain your reasoning. (9-BBN is a sterically hindered

Br H3C C=C Br H HC Figure P18.73 OCH5 OCH5 H KOH KOH HC-C=C-OCH5 (only elimination product observed)

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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