Complete the reactions given in Fig. P17.45 by proposing structures for the major organic products. (a) HC=CH-CH=CH-CHMgBr
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Complete the reactions given in Fig. P17.45 by proposing structures for the major organic products.
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(a) H₂C=CH-CH=CH-CH₂MgBr + D₂O (b) + H₂CH₂ H₂C=CH-CH=CH-CH₂MgBr + H₂C-CH₂ (c) trans-BrCH₂CH=CHCH(CH3)2 + Na+ CH3CH₂S- (d) Same as part (c), but with warm ethanol only; no Na+ CH3CH₂S- (e) (f) H₂C- + N-bromosuccinimide (1 equiv.) CH3 | C-CH3 + N-bromosuccinimide (1 equiv.) T H Brz dark AIBN CCL4 KOH ethanol ethanol C10H8 peroxides CCl4 H3O+ C10H13 Br
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b Two allylic Grignard reagents are in equilibrium and each reacts with DO HCCHCHCHCHMgBr HCCHCHCHCH DO HCCHCHCHCHD MgBr DO HC CHCHCHCH D Note in this ...View the full answer
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