Account for each of the following facts with an explanation. (a) 1,3-Cyclopentadiene is a considerably stronger carbon
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Account for each of the following facts with an explanation.
(a) 1,3-Cyclopentadiene is a considerably stronger carbon acid than 1,4-pentadiene, even though the acidic hydrogens in both cases are doubly allylic.
(b) 3-Bromo-1,4-pentadiene undergoes solvolysis readily in protic solvents, but 5-bromo-1,3-cyclopentadiene is virtually inert.
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a Although the conjugatebase anion of 14pentadiene is doubly allylic and resonance...View the full answer
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