Complete the reactions given in Fig. P22.88 by giving the major organic products. Explain your reasoning. (b)

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Complete the reactions given in Fig. P22.88 by giving the major organic products. Explain your reasoning.

(b) (c) (d) (e) 1-CH-i H3C-C-CH-C-OEt + Br(CH)4Br & y-butyrolactone Cl NO CH3 NO Li* [(CH3)zCH],N: +Na+

(f) (h) (i) CH,(CO,Et)2 + PhCH=0 Na EtO CH2(CO,Et)2 EtOH CI(CH) 3 CH a NH (catalyst) || HCCCH,CO,Et +

(j) (k) (1) (m) MeOC- CH3 H (CH3)2C=C Figure P22.88 + COEt COEt HC HC C-MgBr +PhCH=CHCPh CuCl + CH3MgI + CuCl

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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Question Posted: Dec 07, 2023 05:21 AM

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Complete the reactions given in Fig. P22.88 by giving the major organic products. Explain your reasoning. (b)

Question:

Ⓡ (b) (c) (d) (e) 1-CH₂-i H3C-C-CH₂-C-OEt + Br(CH₂)4Br & y-butyrolactone Cl NO₂ CH3 NO₂ Li* [(CH3)zCH],N: +Na+ :CH(CO₂Et) 2 C-CH3 1) LiAlH4 2) H3O+ CH 31 NaOEt -CO₂Et + CH3CH(CO₂Et)2 EtOH NaOEt (excess) EtOH H3O+ H₂O heat H3O+ heat (C₂H12O)

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a The conjugatebase enolate ion is alkylated by the alkyl halide Then the conjugatebase enolate ion of the alkylation product is formed and reacts int...View the full answer

Organic Chemistry

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