The heat of formation of (E)-1,3-pentadiene is 75.8 kJ mol 1 (18.1 kcal mol 1 ), and
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The heat of formation of (E)-1,3-pentadiene is 75.8 kJ mol–1 (18.1 kcal mol–1), and that of 1,4-pentadiene is 106.3 kJ mol–1 (25.4 kcal mol–1).
(a) Which alkene has the more stable arrangement of bonds?
(b) Calculate the heat liberated when one mole of 1,3-pentadiene is burned. The heat of combustion of carbon is 2393.5 kJ mol–1 (294.05 kcal mol–1), and that of H2 is 2285.8 kJ mol–1 (268.32 kcal mol–1).
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