A gaseous sample consisting of 1.00mol molecules is described by the equation of state pV m =RT(1+Bp).

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A gaseous sample consisting of 1.00mol molecules is described by the equation of state pVm =RT(1+Bp). Initially at 373K, it undergoes Joule–Thomson expansion from 100 atm to 1.00 atm. Given that Cp,m = 5/2 R, μ =0.21K atm−1, B=−0.525(K/T) atm−1 and that these are constant over the temperature range involved, calculate ΔT and ΔS for the gas.

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