a. Using the relationships derived in Example Problem 7.1 and the values of the critical constants for

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a. Using the relationships derived in Example Problem 7.1 and the values of the critical constants for water from Table 7.2, calculate values for the van der Waals parameters a, b, and R from zc , Tc , Pc , and Vc. Do your results agree with those in Tables 1.2 and 7.4 in Appendix A?

b. Calculate the van der Waals parameters a and b using the critical constants for water and the correct value for R. Do these results agree with those in Tables 1.2 and 7.4?

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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