Consider the reaction TiO 2 (s) + 2 C(graphite) + 2 Cl 2 (g) 2 CO(g) +

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Consider the reaction TiO2(s) + 2 C(graphite) + 2 Cl2(g) †’ 2 CO(g) + TiCl4(l) for which ΔHoR ,298 K= €“80. kJ mol€“1. Given the following data at 25°C,

C(graphite) Co(g) TiCl4(1) TiO:(s) Cl:(g) Substance AH, (kJ mol-1) -110.5 -945 55.06 8.53 29.12 33.91 145.2 CP.(JKmol)

Assume that the heat capacities are independent of temperature.

a. Calculate ΔHoR at 135.8ºC, the boiling point of TiCl4.

b. Calculate ΔHof for TiCl4(l) at 25ºC.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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