In this problem, you will carry out the calculations that describe the SternGerlach experiment shown in Figure

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In this problem, you will carry out the calculations that describe the Stern€“Gerlach experiment shown in Figure 17.2. Classically, a magnetic dipole μ has the potential energy E = ˆ’μ €¢ B. If the field has a gradient in the z direction, the magnetic moment will experience a force, leading it to be deflected in the z direction. Because classically μ can take on any value in the range ˆ’ ˆ£Î¼ˆ£ ‰¤ μz‰¤ ˆ£Î¼ˆ£, a continuous range of positive and negative z deflections of a beam along the y direction will be observed. From a quantum mechanical perspective, the forces are the same as in the classical picture, but μ z can only take on a discrete set of values. Therefore, the incident beam will be split into a discrete set of beams that have different deflections in the z direction. 

a. The geometry of the experiment is shown here. In the region of the magnet indicated by d1, the Ag atom experiences a constant force. It continues its motion in the force-free region indicated by d2.

d, -y

If the force inside the magnet is Fz, show that ˆ£zˆ£ = 1/2(Fz/m Ag)t21 + t2vz (t1). The times t1 and t2 correspond to the regions d1 and d2.

b. Show that, assuming a small deflection,

dịd, + -d? 2 |z| = F. .2 тAg У 4g'y

c. The magnetic moment of the electron is given by ˆ£Î¼ˆ£ = gSμB/2. In this equation, μB is the Bohr magneton and has the value 9.274 × 10€“24 J/T. The gyromagnetic ratio of the electron gS has the value 2.00231. If ˆ‚Bz/ˆ‚z = 750. T m€“1, and d1 and d2 are 0.175 and 0.225 m, respectively, and v y = 475 m s€“1, what values of z will be observed?

Figure 17.2

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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