The C 4v group has the following classes: E, 2C 4 , C 2 , 2 v

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The C4v group has the following classes: E, 2C4, C2, 2σv, and 2σd. How many irreducible representations does this group have and what is the dimensionality of each? σd refers to a dihedral mirror plane. For example in the molecule BrF5, the σ v mirror planes each contain two of the equatorial F atoms, whereas the dihedral mirror planes do not contain the equatorial F atoms.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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