The phase diagram of NH 3 can be characterized by the following information. The normal melting and

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The phase diagram of NH3 can be characterized by the following information. The normal melting and boiling temperatures are 195.2 and 239.82 K, respectively; the triple point pressure and temperature are 6077 Pa and 195.41 K, respectively. The critical point parameters are 112.8 × 105 Pa and 405.5 K. Make a sketch of the P–T phase diagram (not necessarily to scale) for NH3. Place a point in the phase diagram for the following conditions.

State which and how many phases are present.

a. 195.41 K, 9506 Pa

b. 195.41 K, 6077 Pa

c. 245.45 K, 101,325 Pa

d. 415 K,

105 × 105 Pa

e. 185.5 K, 6077 Pa

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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