Why does a quantum mechanical system with discrete vibrational energy levels behave as if it has a

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Why does a quantum mechanical system with discrete vibrational energy levels behave as if it has a continuous energy spectrum if the energy difference between vibrational energy levels ΔE satisfies the relationship ΔE ≪ k_BT?

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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Question Posted: Apr 30, 2018 04:28 AM

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Why does a quantum mechanical system with discrete vibrational energy levels behave as if it has a

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Physical Chemistry

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