Look up the equilibrium constant for the ion-pairing reaction in Appendix J. (a) Use the systematic treatment
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Look up the equilibrium constant for the ion-pairing reaction in Appendix J.
(a) Use the systematic treatment of equilibrium to find [Zn2+] in 0.010 F ZnSO4. Neglect activity coefficients and any other reactions.
(b) Use the answer from part (a) to compute the ionic strength and activity coefficients of Zn2+ and SO24-. Then repeat the calculation using activity coefficients. Repeat the procedure two more times to find a good estimate of [Zn2+]. What percentage is ion paired? What is the ionic strength of the solution?
(c) Two possibly important reactions that we did not consider are acid hydrolysis of Zn2+ and base hydrolysis of SO24-. Write these two reactions and find their equilibrium constants in Appendixes I and G.
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