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1. The pyrolysis of ethyl nitrate (C2H5NO3,A) to generate formaldehyde (HCHO, B), methyl nitrite (CH3NO2,D), acetaldehyde (CH3CHO,E), ethanol (C2H5OH,F) and NO2 occurs as per the
1. The pyrolysis of ethyl nitrate (C2H5NO3,A) to generate formaldehyde (HCHO, B), methyl nitrite (CH3NO2,D), acetaldehyde (CH3CHO,E), ethanol (C2H5OH,F) and NO2 occurs as per the mechanism [1,2] (1) A(M1)k1C2H5O(M2)+NO2(M3) (2) C2H5Ok2CH3(M4)+B(M5) (3) A+CH3k3D(M6)+C2H5O (4) 2C2H5Ok4E(M7)+F(M8). (a). Obtain the atomic and stoichiometric matrices for this reaction scheme. Establish from the ranks of these matrices or by other means that all reactions are independent. (b). In view of (a), how many species formation rates are linearly independent? Obtain appropriate stoichiometric relations among rates of formation of various species
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