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3. Consider the methanation of synthesis gas, represented by the overall reaction: 3H2+COCH4+H2O A proposed LHHW-type mechanism is shown below. CO+2SC.S+O.SH2+2S2HSC.S+3H.SCH3.S+3SCH3.S+HSCH4+2S2H.S+O.SH2O+3S Derive a rate expression
3. Consider the methanation of synthesis gas, represented by the overall reaction: 3H2+COCH4+H2O A proposed LHHW-type mechanism is shown below. CO+2SC.S+O.SH2+2S2HSC.S+3H.SCH3.S+3SCH3.S+HSCH4+2S2H.S+O.SH2O+3S Derive a rate expression for the disappearance of CO if step (3) is the rate-determining step. Source: Introduction to Chemical Reactor Analysis, Second Edition
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