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(30 pts) A proposed reaction mechanism is given for the synthesis of methane from syngas (H2 and CO) over a Ru catalyst: Derive the rate

(30 pts) A proposed reaction mechanism is given for the synthesis of methane from syngas (H2 and CO) over a Ru catalyst: Derive the rate law if methylene formation was the rate-limiting step.

image text in transcribed 5. (30 pts) A proposed reaction mechanism is given for the synthesis of methane from syngas (H2 and CO) over a Ru catalyst: CO(g)k1k1CO(ad)CO(ad)k2k2C(ad)+O(ad)O(ad)+H2(g)k3k3H2O(g)H2(g)k4k42H(ad)C(ad)+H(ad)k5k5CH(ad)CH(ad)+H(ad)k6k6CH2(ad)CH2(ad)+H(ad)k7k7CH3(ad)CH3(ad)+H(ad)K8k8CH4(g) Derive the rate law if methylene formation was the rate-limiting step. 5. (30 pts) A proposed reaction mechanism is given for the synthesis of methane from syngas (H2 and CO) over a Ru catalyst: CO(g)k1k1CO(ad)CO(ad)k2k2C(ad)+O(ad)O(ad)+H2(g)k3k3H2O(g)H2(g)k4k42H(ad)C(ad)+H(ad)k5k5CH(ad)CH(ad)+H(ad)k6k6CH2(ad)CH2(ad)+H(ad)k7k7CH3(ad)CH3(ad)+H(ad)K8k8CH4(g) Derive the rate law if methylene formation was the rate-limiting step

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