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3.8 As an approximate rule, a particular vibrational mode in a molecule will contribute to the equipartition principle energy at temperatures where ? KBT >
3.8 As an approximate rule, a particular vibrational mode in a molecule will contribute to the equipartition principle energy at temperatures where ? KBT > we for that mode. In the following table are listed all the vibrational constants for several molecules. A sample of 1.00 mol of one of these molecules is heated from sla- 350 K to 360 K, absorbing 698 J of energy in the pro- cess. Show which molecule is most likely the one in the sample. molecule vibrational constants (cm") 71 71 94 219 224 224 CCl4 217 217 314 314 314 459 776 776 776 CHA 1306 1306 1306 1534 1534 2917 3019 3019 3019 Cl,CO 285 440 567 580 849 1827 CIA 90 90 125 125 125 178 555 555 555
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