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4NH3(g)+5O2(g)4NO(g)+6H2O(g) The feed stream of 4mol/s ammonia (NH3) and 6mol/s of oxygen (O2) enters the reactor at 200C and the product contain no ammonia and
4NH3(g)+5O2(g)4NO(g)+6H2O(g) The feed stream of 4mol/s ammonia (NH3) and 6mol/s of oxygen (O2) enters the reactor at 200C and the product contain no ammonia and leaves at an unknown temperature Tout(C). Because of the limited range of applicability of the heat capacity relations we found two solutions for the exit temperature; namely, 2657K and 3626K. Rework the energy balance using better expression for the heat capacities. Go to: http://webbook.nist.gov/chemistry/ and select Name under Search Options. Fill in the name of the compound and its phase and retrieve the data. You should use the Shomate equations for the ideal gas, constantpressure heat capacity. Plot the Shomate equation for water from 25C to 6000C and compare with the expression given in Murphy on the graph. Show that the Shomate equation can be used down to 298K and give reasonable results. What is the exit temperature when calculated using the Shomate equation? Explain why you now find only one solution
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