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A 100 liter piston-cylinder contains five moles of gas that obey the following equation of state: P RT a + V V2 where a =

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A 100 liter piston-cylinder contains five moles of gas that obey the following equation of state: P RT a + V V2 where a = -4.053 m Pa/mol2. The temperature is initially 300 K. The gas is expanded isothermally until the volume doubles. a) Derive an expression for the change in enthalpy with respect to volume at constant temperature for this gas in terms of measurable quantities. b) Use your expression from a) to calculate the change in enthalpy of the gas as a result of this process. Compare your result to that of an ideal gas

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