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A. Rank the following compounds in order of decreasingacidity, putting the most acidic first. why? CH 3 OCH 3 CH3CHO CH 3 CH2OH CH 3

A. Rank the following compounds in order of decreasingacidity, putting the most acidic first. why?

CH3OCH3 CH3CHO CH3CH2OH CH3COOH

I II III IV

B. Which of the following matches the molecules to thenames of the functional groups? why?

CH3OCH3 Ether

CH3CONH2 Amine

CH3SH Thiol

CH3CHO Alcohol

C. Which of the following compounds has the highestboiling point? why?

image

D. Which of the following molecules are chiral?why?

I. 2-Chlorobutane

II. 3-Bromopentane

III. 2-Methylpropene

IV. 2-Bromo-3-methylbutane

E. What is the relationship between the following 2components?? why?

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Constitutional isomers

Identical

Stereoisomers

Not isomers, different compounds

F. Which of the following has the S Configuration?Why?

image

G. What kind of reaction does theconversion of A to B represent?

image

Acid-base reaction.

Elimination reaction.

Substitution reaction.

Addition reaction.

H. For the following reaction, usethe identity of the alkyl halide and nucleophile to determine whichsubstitution mechanism occurs. Then determine which solvent affordsthe faster reaction.

image

SN1, CH3OH

SN1, DMSO

SN2, CH3OH

SN2, DMSO

I. Which of the following is most likely to reactas a nucleophile rather a base?

image

J. What is the most likely mechanism for thereaction below?

image

SN1

SN2

E1

E2

What is the best choice of reagent to accomplish thefollowing transformation?

image

HCl

SOCl2, pyridine

Cl2

H3O+, H2O

|| E III IV

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